In the scene where Catcher talks with Gwendolyn on the phone when she tells him that she won't have dinner with him and she's reading Down with Love, he rips off his shirt and a button flies off meaning to drop into Peter's martini but you can see it fly across the screen, after it flies away you see something plop into the martini and the vodka ripple.
i agree, most, if not all of the buttons fly off everywhere. it could have been any one of them that you saw. good try though. by the way, have any of you seen the outtakes for that scene? the button manages to land in between David Hyde Pierce's lips! its so funny! lol :-)