Star Wars Episode 6: Return of the Jedi - Luke's Defected Hand
About twenty minutes into the movie, Luke and Han are about to be terminated. In one instance where a blaster shoots Luke's defective hand, it reveals his robotic arm. However, before the blaster's shot hits his hand, you can see the inside of his hand. You should be able to catch this slip-up if you have it on DVD, and can pause it at the exact time it happens.