Italian Job, The (2003) - Spiderman Comes to Save the Day
Ok, it happens right when the car goes through the ground. Spiderman pops up out of know where. The exact time frame was Chapter 14, 89 min and 11 sec. It is pretty easy to spot if you know what you are looking for.
There are people walking around on Hollywood Blvd. in various movie costumes all the time. They are actually hired for the purpose of tourists taking pictures. Since this movie was being filmed around the time the first Spider-Man movie came out, he would be one of the more visible characters.
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