The episodes 'This Year's Girl' and 'Who Are You' are continued straight on from each other, but if you watch carefully at Buffy's hair right at the end of 'This Year's Girl' and right at the beginning of 'Who Are You', you can see her hair is straight, but a few seconds later her hair is curly. I don't know about you, but my hair never does that by it self.
Buffy's hair has been straightened for the episode "This year's girl". In the following episode "Buffy" takes a bath - you will notice when her hair is wet it becomes curly (due to the perm we see in other episodes). Hope this explains it!